Photolyses of mammalian carboxy-hemoglobin studied by photoacoustic calorimetry

The enthalpy and conformational volume changes in the photolyses of carboxy-hemoglobin (HbCO) of human, bovine, pig, horse and rabbit are investigated by photoacoustic calorimetry. Considering the time scales of the exciting laser pulse and the receiving ultrasound transducers (PVDF films and PZT ceramics), as well as the reaction lifetimes in the photolysis processes of HbCO, the measured results are related to the geminate recombination and tertiary relaxation in photolyses of HbCO. Moreover, the quantum yields of the five mammals are also measured by laser pump-probe technique. The results show that the dynamic parameters, such as enthalpy and conformational volume changes, differ between the processes of the geminate recombination and tertiary relaxation. Also, the dynamic parameters differ among the five mammals although some of them may be consistent with each other.     

Silver(I)-mediated reaction of trimethylsilylated arylacetylenes with sulfonyl chlorides:Unexpected formation of vinvl sulfones

A novel reaction of trimethylsilylated arylacetylenes with sulfonyl chlorides was performed in the presence of silver nitrate or triflate.Conjugated vinyl sulfones as dramatic products were obtained in moderate yields and with Z-selectivity.A free radical mechanism has been proposed to account for the formation of the products.     

Generation of Bell states via Lyapunov control on a two-qubit system with an anisotropic XY Heisenberg interaction

We demonstrate that an arbitrary Bell state can be achieved in a two qubit anisotropic Heisenberg XY chain via Lyapunov control. During the whole process, we only need to apply an external field along a given direction to a single qubit. This control strategy is effective for all initial states in the four-dimensional Hilbert space where the target state is asymptotically stable. The effects of imperfections on the fidelity for the target state such as Gaussian leakage of local control and localized dephasi...     

Connected cubic s-arc-regular Cayley graphs of finite nonabelian simple groups

A graph is said to be s-arc-regular if its full automorphism group acts regularly on the set of its s-arcs. In this paper, we investigate connected cubic s-arc-regular Cayley graphs of finite nonabelian simple groups. Two suffcient and necessary conditions for such graphs to be 1- or 2-arc-regular are given and based on the conditions, several infinite families of 1-or 2-arc-regular cubic Cayley graphs of alternating groups are constructed.     

An efficient synthesis of 2-(guaiazulen-1-yl)furan derivatives via intramolecular Wittig reactions

An efficient and mild synthesis of 2-(guaiazulen-1-yl)furans,starting from easily accessible 1-(3-aryl-2-cyanopropenoyl) guaiazulenes,tributylphosphine and acyl chlorides,is described.The strategy employs the intramolecular Wittig protocol as a key step to append the crticial furan ring,leading to the highly functional furans in good yields.     

分段滤波用于消除脉搏血氧检测中多种运动干扰的研究

脉搏血氧饱和度检测仪可以无损、实时地检测动脉血液中的含氧百分比,从而快速对人体的呼吸状况以及心肺功能作出判断,但其检测精度极易受到测试部位运动的影响.人体测试部位的运动大致可以分为突发性运动干扰以及周期性的运动干扰.突发性干扰表现在局部脉搏波的波形突变上,而周期性的干扰体现在多个局部脉搏波的波形的周期性变化上.文章有针对性地提出了一种将微分阈值分段与迭带中值滤波相结合的方法来剔除突发扰动的方法,并且在上诉方法上再加上一级多点移动平滑以消除周期性运动干扰.实验证明该方法在消除多种运动伪差上有着较好的效果,且该方法计算简单,易于实现,有着一定的实际应用价值.     

外源一氧化氮对镉胁迫下番茄幼苗叶绿体保护作用的光谱学分析

镉（Cd）是重要的重金属污染源，一氧化氮（NO）是近年来发现的一种普遍存在于生物界的信使分子，研究表明其参与了植物对Cd胁迫的应答反应调控。文章用硝普纳（SNP）作为NO供体，向番茄幼苗喷洒100mol·L^-1SNP1d后加入50mol·L^-1Cd处理7d，取完全展开叶片，提取叶绿体进行光谱学研究，分别测定了叶绿体室温吸收光谱、叶绿体低温荧光光谱和DCPIP电子传递效率等指标，研究外源NO缓解Cd对叶绿体毒性的影响。结果发现，CA对叶绿素a、叶绿素b和类胡萝b素含量都有不同程度的降低，NO处理缓解了CA的影响，使叶绿体室温吸收光谱的吸收率提高；CA导致686nm处峰（PSII）偏移4nrn，峰值降低33％，734nm处峰值降低23％，外源NO缓解了Cd对光合系统的影响，使得叶绿体低温荧光光谱在686和734nm的峰值分别仅下降17％和100o；以DCPIP为人工电子受体，Cd处理的叶绿体中DCPIP还原速率较慢，光合电子传递（H2O→DCPIP）速率降低1．5倍，外源NO处理显著缓解了Cd对电子传递链的抑制，使其光合电子传递速率恢复到对照的水平。该研究可为NO处理增强植物对Cd胁迫的抗性提供理论依据。     

Effects of source opacity and expansion on two-pion Bose-Einstein correlations

We examine two-pion Bose-Einstein correlations for partially coherent particle-emitting sources within quantum statistical formalism, where the sources are treated as classical currents with chaotic and coherent components. The two-pion correlation functions of the partially coherent sources contain a phase which is sensitive to the asymmetry of the source emission function. We investigate the influence of source opacity and expansion in high energy heavy ion collisions on the phase by Monte Carlo calculati...     

Synthesis of SnO_2 nanorods from aqueous solution:The effect of preparation conditions on the formed patterns

<正>SnO_2 nanorods were deposited on the Si substrates in an aqueous solution containing both SnCl_4 and CO(NH_2)_2.It is found that different self-assembled patterns of SnO_2 nanorods can be obtained by changing the deposition conditions such as the molar ratio of CO(NH_2)_2 to SnCl_4 and the pretreatment of the substrate.Scattered SnO_2 nanorods,for example,can be changed into flower-like patterns when the molar ratio of CO(NH_2)_2 to SnCl_4 is raised,and well-aligned nanorod arrays can be formed when the pretreatment of the substrate is changed.In addition,some interesting patterns,e.g.tree-like patterns,can also be observed.     

The multi-concentration and two-dimensional capillary electrophoresis method for the analysis of drugs in urine samples

A novel method has been developed by integration of multi-concentration and two-dimensional(2D) capillary electrophoresis(CE) for simultaneous enhancement of detection sensitivity and separation power in complex samples.Capillary zone electrophoresis(CZE) was used as the first dimension separation according to mobilities,from which the effluent fractions were further analyzed by micellar electrokinetic capillary chromatography(MEKC) acting as the second dimension.Cation-selective exhaustive injection(CSEI) ...